Thermophotovoltaic (TPV) energy conversion is a direct conversion process from heat to electricity via photons. A basic thermophotovoltaic system consists of a thermal emitter and a photovoltaic diode cell.
The temperature of the thermal emitter varies between different systems from about 900 °C to about 1300 °C, although in principle TPV devices can extract energy from any emitter with temperature elevated above that of the photovoltaic device (forming an optical heat engine). The emitter can be a piece of solid material or a specially engineered structure. Thermal emission is the spontaneous emission of photons due to thermal motion of charges in the material. For these TPV temperatures, this radiation is mostly at near infrared and infrared frequencies. The photovoltaic diodes absorbs some of these radiated photons and converts them into electricity.
Thermophotovoltaic systems have few to no moving parts and are therefore quiet and require little maintenance. These properties make thermophotovoltaic systems suitable for remote-site and portable electricity-generating applications. Their efficiency-cost properties, however, are often poor compared to other electricity-generating technologies. Current research in the area aims at increasing system efficiencies while keeping the system cost low.
TPV systems usually attempt to match the optical properties of thermal emission (wavelength, polarization, direction) with the most efficient absorption characteristics of the photovoltaic cell, since unconverted thermal emission is a major source of inefficiency. Most groups focus on gallium antimonide (GaSb) cells. Germanium (Ge) is also suitable. Much research and development concerns methods for controlling the emitter's properties.
TPV cells have been proposed as auxiliary power conversion devices for capture of otherwise lost heat in other power generation systems, such as steam turbine systems or solar cells.
A prototype TPV hybrid car was built, the "Viking 29" (TPV) powered automobile, designed and built by the Vehicle Research Institute (VRI) at Western Washington University.
TPV research is an active area. Among others, the University of Houston TPV Radioisotope Power Conversion Technology development effort is attempting to combine a thermophotovoltaic cell with thermocouples to provide a 3 to 4-fold improvement in system efficiency over current radioisotope thermoelectric generators.
In TPV cells, the photovoltaic photodiode is on the cooler side of the heat engine. This should not be confused with "thermoradiative" or "negative emission" cells in which the photodiode is on the hotter side of the heat engine. Photovoltaics in general operate at lower efficiency as the temperature increases, and in TPV systems, keeping the photovoltaic cool is a significant challenge. However, systems have also been proposed that use a thermoradiative device as an emitter in a TPV system, theoretically allowing power to be extracted from both a hot photodiode and a cold photodiode.
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